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Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K

หน่วยงาน Edinburgh Research Archive, United Kingdom

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ชื่อเรื่อง : Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K
นักวิจัย : Harrison, Mark A J , Cape, J Neil , Heal, Mathew R
คำค้น : partitioning , aqueous solubility , physical chemistry
หน่วยงาน : Edinburgh Research Archive, United Kingdom
ผู้ร่วมงาน : -
ปีพิมพ์ : 2545
อ้างอิง : Harrison, M. A. J., Cape, J. N. and Heal, M. R. (2002) Experimentally determined Henry's law coefficient of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K, Atmos. Environ. 36, 1843-1851. , http://hdl.handle.net/1842/2483
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : -
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The Henry’s Law coefficient is a key physical parameter in the partitioning, and hence environmental fate, of a chemical species between air and water. Despite the acknowledged polluting potential of phenol, 2-methylphenol (o-cresol) and 2-nitrophenol, there is extremely poor agreement in the literature of their Henry’s law coefficients and, in particular, no apparent systematic measurement of the variation with temperature. Here a temperature controlled column-stripping method was employed to determine the Henry's Law coefficients for these compounds over the temperature range 281-302 K. Coefficients were derived from regression fits to the observed rates of loss from the liquid phase as a function of column depth in order explicitly to take account of potential non-attainment of equilibrium between liquid and gas phases. Temperature dependent expressions summarising the Henry's Law coefficient of phenol, o-cresol and 2-nitrophenol over the stated temperature range are ln H (/ M atm-1) = 5850/T - 11.6, ln H (/ M atm-1) = 6680/T - 15.4 and ln H (/ M atm-1) = 6270/T - 16.6, respectively (to within 15% of all measured values in this work). A thorough comparison with previous literature-published values has been undertaken.

บรรณานุกรม :
Harrison, Mark A J , Cape, J Neil , Heal, Mathew R . (2545). Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K.
    กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom .
Harrison, Mark A J , Cape, J Neil , Heal, Mathew R . 2545. "Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K".
    กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom .
Harrison, Mark A J , Cape, J Neil , Heal, Mathew R . "Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K."
    กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom , 2545. Print.
Harrison, Mark A J , Cape, J Neil , Heal, Mathew R . Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K. กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom ; 2545.