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Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions.

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions.
นักวิจัย : Luo, Ding.
คำค้น : DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2553
อ้างอิง : Luo, D. (2010). Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions. Doctoral thesis, Nanyang Technological University, Singapore. , http://hdl.handle.net/10356/41625
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : -
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

This thesis describes the asymmetric syntheses of bifunctionalized phosphine complexes, which contain a stereogenic center at phosphorus, through various reactions, including insertion, hydrophosphination, hydration, and hydroamination. Promoted by the coordination of diprop-1-ynylphenylphosphine to ruthenium, the two alkyne moieties thereafter were functionalized by different reactions, which thus led to the formation of a chiral phosphorous center. This strategy presented is valuable and can be widely used in the synthesis of chiral phosphines.

บรรณานุกรม :
Luo, Ding. . (2553). Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions..
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Luo, Ding. . 2553. "Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions.".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Luo, Ding. . "Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions.."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2553. Print.
Luo, Ding. . Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions.. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2553.