| ชื่อเรื่อง | : | Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile : half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X) |
| นักวิจัย | : | Mak, Garvin Kar Hang , Chan, Pek Ke , Fan, Wai Yip , Leong, Weng Kee , Li, Yongxin |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds. |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2556 |
| อ้างอิง | : | Mak, K. H. G., Chan, P. K., Fan, W. Y., Leong, W. K., & Li, Y. (2013). Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile: Half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X). Journal of Organometallic Chemistry, 741-742, 176-180. , 0022-328X , http://hdl.handle.net/10220/18614 , http://dx.doi.org/10.1016/j.jorganchem.2013.05.038 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Journal of organometallic chemistry |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | The reaction of Cp*Ir(CO)2 (1) with pentafluorobenzontrile in the presence of a base afforded the diaryl complex Cp*Ir(CO)(p-C6F4CN)2 (4). The reaction proceeds via the metallacarboxylic acid Cp*Ir(CO)(p-C6F4CN)(COOH) (2). The latter can be decarboxylated in the presence of a base to the hydrido species Cp*Ir(CO)(p-C6F4CN)(H) (5), which can then undergo hydride–chloride exchange to Cp*Ir(CO)(p-C6F4CN)(Cl) (6a). In the presence of air and water, the reaction of 1 with pentafluorobenzontrile afforded a complex formulated as Cp*Ir(CO)(p-C6F4CN){C(OH)(NH2)C6F5} (7a); this is also available from the reaction of 2 with pentafluorobenzamide in the presence of aqueous NaOH. MOE (Min. of Education, S’pore) |
| บรรณานุกรม | : |
Mak, Garvin Kar Hang , Chan, Pek Ke , Fan, Wai Yip , Leong, Weng Kee , Li, Yongxin . (2556). Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile : half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X).
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Mak, Garvin Kar Hang , Chan, Pek Ke , Fan, Wai Yip , Leong, Weng Kee , Li, Yongxin . 2556. "Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile : half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X)".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Mak, Garvin Kar Hang , Chan, Pek Ke , Fan, Wai Yip , Leong, Weng Kee , Li, Yongxin . "Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile : half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X)."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2556. Print. Mak, Garvin Kar Hang , Chan, Pek Ke , Fan, Wai Yip , Leong, Weng Kee , Li, Yongxin . Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile : half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X). กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2556.
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