A small disk extraction method (I.D. 13 mm) wasdeveloped for determination of 16 PAHs, EPA prioritypollutants, from water samples. It was cost-effective,time-saving, and non-toxic method. Factors affectingthe recoveries of PAHs such as solubilizerconcentration, volume of eluting solvent, elution time,and breakthrough volume were studied. The presence of0.30 mM Brij-35 was most appropriate for the enrichmentof PAHs on C(,18) disk. Elution with 0.50 mLacetonitrile gave the high recoveries and therecoveries did not change significantly after 15 min ofelution. Optimum solution volume was 100 mL. The methoddetection limit was found to range from less than 0.01ppb to 0.20 ppb. The recoveries varied from 72.88 to117.12% with percent relative standard deviation (%R.S.D.) between 1.96 and 4.82% except Anthracene was55.09% recovery. Percent error of this method were inthe range of 0.65-9.58%. Moreover, this extractionmethod was applied to determine PAHs in real watersamples.