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Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds

หน่วยงาน National Institute Of Oceanography (NIO), India

รายละเอียด

ชื่อเรื่อง : Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds
นักวิจัย : Singh, K.S. , Kaminsky, W.
คำค้น : ligands , alkynes
หน่วยงาน : National Institute Of Oceanography (NIO), India
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : Polyhedron, vol.68; 2014; 279–286 , http://drs.nio.org/drs/handle/2264/4462
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : -
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The arene ruthenium(II) azido compounds [{(p-cymene)Ru(N^O)N3}] have been prepared by the reaction of [{(p-cymene)Ru(mewN3)Cl}2] with the corresponding ligands. The ruthenium azido compounds [{(p-cymene)Ru(N^O)N3}] undergo 1,3-dipolar additions with substituted alkynes at room temperature to give the (eta6-arene) ruthenium triazolato compounds [(p-cymene)Ru(N^O){N3C2(CO2R)2}]. The compounds were characterized on the basis of FTIR, NMR (1H and 13C) and the molecular structure of a representative compound has been established with the help of single crystal X-ray diffraction.

บรรณานุกรม :
Singh, K.S. , Kaminsky, W. . (2557). Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds.
    : National Institute Of Oceanography (NIO), India.
Singh, K.S. , Kaminsky, W. . 2557. "Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds".
    : National Institute Of Oceanography (NIO), India.
Singh, K.S. , Kaminsky, W. . "Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds."
    : National Institute Of Oceanography (NIO), India, 2557. Print.
Singh, K.S. , Kaminsky, W. . Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds. : National Institute Of Oceanography (NIO), India; 2557.