This thesis presents a measurement of the effective B0s decay width, ΓFS, from a single exponential fit to the flavour-specific decay channel B0s → D-s π +. This measurement is based on an integrated luminosity of 340 pb-1 recorded by LHCb in 2011 at a center of mass energy of 7TeV. The dataset is divided into two exclusive selections. B0s → D-s (( ϕ →K-K+) π-)π + only has a significant background contribution arising from combinatorial background, and the modelling of this is determined entirely by the data. B0s → D-s ((K-K* (892)0 → K+ π-))π + has a larger contribution from combinatoric and mis-identified background and provides an alternative measurement. A simultaneous fit for the effective B0s decay width is performed to both the datasets leading to the result: ΓFS = 0:668 ± 0:017 ± 0:031 ps-1 The result is then combined with information from the LHCb B0s → J/ψØ analysis leading to an improved measurement of the average B0 s decay width: Γs = 0:666 ± 0:010 ± 0:031 ps-1