| ชื่อเรื่อง | : | A cascade thermal isomerisation of cyclobutane di-(carbomethoxy) Δ2-1,2,3-triazolines with intramolecular 1,3-dipolar cycloreversion as the key step |
| นักวิจัย | : | Margetic, Davor. , Warrener, Ronald Norman. , Butler, Douglas N. , Jin, Chuan-Ming. |
| คำค้น | : | Isomerization. , 970103 Expanding Knowledge in the Chemical Sciences. , 030799 Theoretical and Computational Chemistry not elsewhere classified , Cyclobutane. , Rearrangement -- Dipolar cycloaddition -- Reaction mechanism -- Nitrogen heterocycles -- Cycloreversion -- Computational chemistry , Journal Article. Refereed, Scholarly Journal |
| หน่วยงาน | : | Central Queensland University, Australia |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2555 |
| อ้างอิง | : | http://hdl.cqu.edu.au/10018/937474 |
| ที่มา | : | Margetić, D, Warrener, RN, Butler, DN & Jin, C 2012, 'A cascade thermal isomerisation of cyclobutane di-(carbomethoxy) Δ2-1,2,3-triazolines with intramolecular 1,3-dipolar cycloreversion as the key step', Tetrahedron, vol. 68, no. 16, pp. 3306-3318, http://dx.doi.org/10.1016/j.tet.2012.02.073 |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Tetrahedron. United Kingdom : Pergamon, 2012. Vol. 68, no. 16 (2012), p. 3306-3318 13 pages Refereed 0040-4020 1464-5416 (online) , ACQUIRE [electronic resource] : Central Queensland University Institutional Repository. |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | Unprecedented thermal isomerisation of the strained ∆2-1,2,3-triazolines led to the formation of products possessing a novel 1,2,7-triaza-[3.3.0]octa-2-ene ring system incorporated in a norbornane framework. Experimental evidence and quantum chemical calculations have been used to support a postulated reaction mechanism involving as the first step, a rare example of intramolecular 1,3-dipolar cyclo-reversion. Subsequently, several steps involving 1,3-dipolar ring closure, hydrogen shifts and an intramolecular addition are postulated leading to the observed product of this deep-seated isomerisation. The influence of changing substituents on the product outcome of this novel reaction cascade was also studied. |
| บรรณานุกรม | : |
Margetic, Davor. , Warrener, Ronald Norman. , Butler, Douglas N. , Jin, Chuan-Ming. . (2555). A cascade thermal isomerisation of cyclobutane di-(carbomethoxy) Δ2-1,2,3-triazolines with intramolecular 1,3-dipolar cycloreversion as the key step.
กรุงเทพมหานคร : Central Queensland University, Australia. Margetic, Davor. , Warrener, Ronald Norman. , Butler, Douglas N. , Jin, Chuan-Ming. . 2555. "A cascade thermal isomerisation of cyclobutane di-(carbomethoxy) Δ2-1,2,3-triazolines with intramolecular 1,3-dipolar cycloreversion as the key step".
กรุงเทพมหานคร : Central Queensland University, Australia. Margetic, Davor. , Warrener, Ronald Norman. , Butler, Douglas N. , Jin, Chuan-Ming. . "A cascade thermal isomerisation of cyclobutane di-(carbomethoxy) Δ2-1,2,3-triazolines with intramolecular 1,3-dipolar cycloreversion as the key step."
กรุงเทพมหานคร : Central Queensland University, Australia, 2555. Print. Margetic, Davor. , Warrener, Ronald Norman. , Butler, Douglas N. , Jin, Chuan-Ming. . A cascade thermal isomerisation of cyclobutane di-(carbomethoxy) Δ2-1,2,3-triazolines with intramolecular 1,3-dipolar cycloreversion as the key step. กรุงเทพมหานคร : Central Queensland University, Australia; 2555.
|
ridm@nrct.go.th ระบบคลังข้อมูลงานวิจัยไทย รายการโปรดที่คุณเลือกไว้
