| ชื่อเรื่อง | : | Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway |
| นักวิจัย | : | Xiang, Shaohua , Hoang, Kim Le Mai , He, Jingxi , Tan, Yu Jia , Liu, Xue-Wei |
| คำค้น | : | DRNTU::Science::Chemistry::Physical chemistry::Stereochemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2558 |
| อ้างอิง | : | Xiang, S., Hoang, K. L. M., He, J., Tan, Y. J., & Liu, X.-W. (2015). Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway. Angewandte chemie International edition, 54(2), 604-607. , 1433-7851 , http://hdl.handle.net/10220/25100 , http://dx.doi.org/10.1002/anie.201408739 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Angewandte chemie International edition |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | An efficient and concise method for the construction of various O-glycosidic bonds by a palladium-catalyzed reaction with a 3-O-picoloyl glucal has been developed. The stereochemistry of the anomeric center derives from either an inner-sphere or outer-sphere pathway. Harder nucleophiles, such as aliphatic alcohols and sodium phenoxides give β-products, and α products result from using softer nucleophiles, such as phenol. |
| บรรณานุกรม | : |
Xiang, Shaohua , Hoang, Kim Le Mai , He, Jingxi , Tan, Yu Jia , Liu, Xue-Wei . (2558). Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Xiang, Shaohua , Hoang, Kim Le Mai , He, Jingxi , Tan, Yu Jia , Liu, Xue-Wei . 2558. "Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Xiang, Shaohua , Hoang, Kim Le Mai , He, Jingxi , Tan, Yu Jia , Liu, Xue-Wei . "Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2558. Print. Xiang, Shaohua , Hoang, Kim Le Mai , He, Jingxi , Tan, Yu Jia , Liu, Xue-Wei . Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2558.
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