In this work, a cermet (ceramic-metal) membrane was fabricated to separate hydrogen from syngas generation process. An Al2O3 disk support (13 mm diameter) was prepared by uniaxially pressing Al2O3 powder to form monolithic shape at 7 MPa and sintered at 1000-1200 C for 2h. The pore size of 150-160 nm and 50-60 % porosity were determined by Hg porosimetry. The Al2O3 support was then soaked into 10wt% Nickle (II) nitrate hexahydrate solution. Ni solution was applied onto both front and back sides of membrane each for 10 min. After soaking process, the coated Ni-Al2O3 membrane was dried at 25C for 5 h, then at 100C for 24 h and calcined at 900C for 2h. The soaking-drying-firing sequence was repeated ten times to confirm a sufficient amount of Ni was deposited. Finally, calcined Ni-Al2O3 membrane was reduced under H2 atmosphere at 910C for 2h. The crystalline phases of membrane were investigated by XRD. The microstructure and elemental distribution of membranes were also characterized by scanning electron microscopy (SEM) and energy dispersive X-ray spectrometer. The pore size and porosity were determined by Hg porosimetry.