Ferric ion was introduced to the commercial photocatalyst P25 (Degussa) by ultrasonic wet impregnation technique. The concentration of the dopant was varied from 0.0 to 3.0% Fe/Ti ratio. The doped TiO(2) was then loaded to alumina balls using mechanical coating technique and followed by calcination in air at 400, 450, 500 and 550 degrees C. The fabricated photocatalyst was characterized by X-ray diffraction, N(2) adsorption-desorption isotherms, scanning electron microscopy, UV-Vis diffuse reflectance spectroscopy, X-ray adsorption near edge structure and photoluminescence spectroscopy. The photocatalytic activity was tested by following the degradation of methylene blue (MB). It was found that the Fe(3+) doped TiO(2)/Al(2)O(3) has a combination of anatase and rutile phase and free of iron oxide phases. The optimum calcination temperature is 400 degrees C with 0.1% Fe(3+) concentration. The catalyst addresses the entrainment in photocatalytic reactors, eliminating the need for a post filtration process.