| ชื่อเรื่อง | : | Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides |
| นักวิจัย | : | Wang, Yi-Feng , Lonca, Geoffroy Hervé , Le Runigo, Maïwenn , Chiba, Shunsuke |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Wang, Y.-F., Lonca, G. H., Le Runigo, M., & Chiba, S. (2014). Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides. Organic letters, 16(16), 4272-4275. , http://hdl.handle.net/10220/24553 , http://dx.doi.org/10.1021/ol501997n |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Organic letters |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | Radical perfluoroalkylation of α-(biaryl-2-yl)vinyl azides is capable of supplying polyfluoroalkyl aza-polycyclic aromatic hydrocarbons (aza-PAHs). Commercially available Me3SiRf (Rf = CF3, C2F5, and C3F7) are employed as the sources of perfluoroalkyl radicals upon oxidation with PhI(OAc)2. The addition of perfluoroalkyl radicals to biarylvinyl azides generates the corresponding iminyl radicals, which subsequently cyclize with the intramolecular arene moiety, furnishing aza-PAH skeletons having polyfluoroalkyl (RfCH2) function. MOE (Min. of Education, S’pore) |
| บรรณานุกรม | : |
Wang, Yi-Feng , Lonca, Geoffroy Hervé , Le Runigo, Maïwenn , Chiba, Shunsuke . (2557). Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Wang, Yi-Feng , Lonca, Geoffroy Hervé , Le Runigo, Maïwenn , Chiba, Shunsuke . 2557. "Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Wang, Yi-Feng , Lonca, Geoffroy Hervé , Le Runigo, Maïwenn , Chiba, Shunsuke . "Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Wang, Yi-Feng , Lonca, Geoffroy Hervé , Le Runigo, Maïwenn , Chiba, Shunsuke . Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
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