| ชื่อเรื่อง | : | Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile |
| นักวิจัย | : | Kong, Ling Bing , Li, Yongxin , Ganguly, Rakesh , Vidovic, Dragoslav , Kinjo, Rei |
| คำค้น | : | DRNTU::Science::Chemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Kong, L., Li, Y., Ganguly, R., Vidovic, D., & Kinjo, R. (2014). Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile. Angewandte Chemie International Edition, 53(35), 9280-9283. , 1433-7851 , http://hdl.handle.net/10220/20493 , http://dx.doi.org/10.1002/anie.201405201 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Angewandte Chemie international edition |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | An isolable phenylborylene species supported by two oxazol-2-ylidene ligands was synthesized and structurally characterized. Computational studies revealed the presence of lone-pair electrons on the boron atom in this molecule; therefore, there are eight electrons around the three-coordinate boron center. The nucleophilic property was confirmed by the reactions with trifluoromethanesulfonic acid and [(thf)Cr(CO)5], which gave the corresponding conjugate acid and a chromium–borylene complex, respectively. |
| บรรณานุกรม | : |
Kong, Ling Bing , Li, Yongxin , Ganguly, Rakesh , Vidovic, Dragoslav , Kinjo, Rei . (2557). Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Kong, Ling Bing , Li, Yongxin , Ganguly, Rakesh , Vidovic, Dragoslav , Kinjo, Rei . 2557. "Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Kong, Ling Bing , Li, Yongxin , Ganguly, Rakesh , Vidovic, Dragoslav , Kinjo, Rei . "Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Kong, Ling Bing , Li, Yongxin , Ganguly, Rakesh , Vidovic, Dragoslav , Kinjo, Rei . Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
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