| ชื่อเรื่อง | : | Synthesis of N-heterocyclic carbene stabilized catecholatoborenium cations by ligand substitution |
| นักวิจัย | : | Do, Dinh Cao Huan , Muthaiah, Senthilkumar , Ganguly, Rakesh , Vidović, Dragoslav |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Do, D. C. H., Muthaiah, S., Ganguly, R., & Vidović, D. (2014). Synthesis of N-Heterocyclic Carbene Stabilized Catecholatoborenium Cations by Ligand Substitution. Organometallics, 33(16), 4165-4168. , http://hdl.handle.net/10220/20516 , http://dx.doi.org/10.1021/om500434r |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Organometallics |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | Ligand substitution is not a common procedure for the preparation of different borenium cations. This work demonstrates that the chloride ligands of several NHC-stabilized dichloroborenium cations [NHC·BCl2][X] (NHC = (R′C)2(NR)2C; 1, R = iPr, R′ = H; 2, R = iPr, R′ = Me; 3, R = tBu, R′ = H; X = AlCl4, B(3,5-Cl2-C6H3)4) could be replaced with a catecholato moiety to produce [NHC·Bcat][X]. According to single-crystal X-ray analyses this particular ligand exchange enhanced the Lewis acidity of the target borocations with respect to the dichloro precursors. ASTAR (Agency for Sci., Tech. and Research, S’pore) |
| บรรณานุกรม | : |
Do, Dinh Cao Huan , Muthaiah, Senthilkumar , Ganguly, Rakesh , Vidović, Dragoslav . (2557). Synthesis of N-heterocyclic carbene stabilized catecholatoborenium cations by ligand substitution.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Do, Dinh Cao Huan , Muthaiah, Senthilkumar , Ganguly, Rakesh , Vidović, Dragoslav . 2557. "Synthesis of N-heterocyclic carbene stabilized catecholatoborenium cations by ligand substitution".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Do, Dinh Cao Huan , Muthaiah, Senthilkumar , Ganguly, Rakesh , Vidović, Dragoslav . "Synthesis of N-heterocyclic carbene stabilized catecholatoborenium cations by ligand substitution."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Do, Dinh Cao Huan , Muthaiah, Senthilkumar , Ganguly, Rakesh , Vidović, Dragoslav . Synthesis of N-heterocyclic carbene stabilized catecholatoborenium cations by ligand substitution. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
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