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Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization
นักวิจัย : Zeng, Xin , Tai, Kong Fai , Zhang, Tianliang , Ho, Chun Wan John , Chen, Xiaodong , Huan, Alfred , Sum, Tze Chien , Wong, Lydia H.
คำค้น : DRNTU::Engineering::Materials
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : Zeng, X., Tai, K. F., Zhang, T., Ho, C. W. J., Chen, X., Huan, A., Sum, T. C., & Wong, L. H. (2014). Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization. Solar Energy Materials and Solar Cells, 124, 55-60. , 0927-0248 , http://hdl.handle.net/10220/20233 , http://dx.doi.org/10.1016/j.solmat.2014.01.029 , 180308
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Solar energy materials and solar cells
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Kesterite thin film solar cell has been fabricated by chemical spray pyrolysis (CSP) of an aqueous solution followed by high temperature selenization. The pyrolysis formation of Cu2ZnSnS4 was conducted in atmospheric condition with substrate temperature of 280 °C. X-ray diffraction and Raman spectroscopy study confirmed the formation of the single phase Cu2ZnSn(S,Se)4 kesterite structure after selenization without traceable secondary phases. FESEM image shows a uniform absorber layer without carbon layer formed between CZTSSe and Mo. Power conversion efficiency of 5.1% was obtained with different amounts of selenium incorporation. Power dependent and temperature dependent photoluminescence (PL) study revealed donor-to-acceptor pairs (DAP) transition at low temperature. Severe PL quenching at temperatures above 41 K is attributed to the opening of non-radiative recombination channels from the defects associated with non-stoichiometric elemental ratio. Therefore, further enhancement of power conversion efficiency can be achieved by better control of stoichiometry.

บรรณานุกรม :
Zeng, Xin , Tai, Kong Fai , Zhang, Tianliang , Ho, Chun Wan John , Chen, Xiaodong , Huan, Alfred , Sum, Tze Chien , Wong, Lydia H. . (2557). Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Zeng, Xin , Tai, Kong Fai , Zhang, Tianliang , Ho, Chun Wan John , Chen, Xiaodong , Huan, Alfred , Sum, Tze Chien , Wong, Lydia H. . 2557. "Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Zeng, Xin , Tai, Kong Fai , Zhang, Tianliang , Ho, Chun Wan John , Chen, Xiaodong , Huan, Alfred , Sum, Tze Chien , Wong, Lydia H. . "Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print.
Zeng, Xin , Tai, Kong Fai , Zhang, Tianliang , Ho, Chun Wan John , Chen, Xiaodong , Huan, Alfred , Sum, Tze Chien , Wong, Lydia H. . Cu2ZnSn(S,Se)4 kesterite solar cell with 5.1% efficiency using spray pyrolysis of aqueous precursor solution followed by selenization. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.