| ชื่อเรื่อง | : | Catalytic asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates: access to chiral trifluoromethylated tertiary thioethers and thiols |
| นักวิจัย | : | Chen, Wenchao , Jing, Zhengzhong , Chin, Kek Foo , Qiao, Baokun , Zhao, Yan , Yan, Lin , Tan, Choon-Hong , Jiang, Zhiyong |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Chen, W., Jing, Z., Chin, K. F., Qiao, B., Zhao, Y., Yan, L., et al. (2014). Catalytic Asymmetric Conjugate Addition of Mercaptans to β-Substituted-β-Trifluoromethyl Oxazolidinone Enoates: Access to Chiral Trifluoromethylated Tertiary Thioethers and Thiols. Advanced Synthesis & Catalysis, 356(6), 1292-1300. , 1615-4150 , http://hdl.handle.net/10220/19696 , http://dx.doi.org/10.1002/adsc.201301027 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Advanced synthesis & catalysis |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | The first asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates has been developed. The opposite enantiomers of adducts, containing a trifluoromethylated hetero-quaternary stereogenic centers, could be obtained by utilizing two pseudo-enantiomeric Cinchona alkaloid-derived tertiary amine/squaramides as catalysts. Potassium dihydrogen phosphate was found to accelerate the reaction rate without compromising the enantioselective excess. A variety of chiral trifluoromethylated tertiary thioethers and thiols were readily prepared with excellent enantioselectivity. |
| บรรณานุกรม | : |
Chen, Wenchao , Jing, Zhengzhong , Chin, Kek Foo , Qiao, Baokun , Zhao, Yan , Yan, Lin , Tan, Choon-Hong , Jiang, Zhiyong . (2557). Catalytic asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates: access to chiral trifluoromethylated tertiary thioethers and thiols.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Chen, Wenchao , Jing, Zhengzhong , Chin, Kek Foo , Qiao, Baokun , Zhao, Yan , Yan, Lin , Tan, Choon-Hong , Jiang, Zhiyong . 2557. "Catalytic asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates: access to chiral trifluoromethylated tertiary thioethers and thiols".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Chen, Wenchao , Jing, Zhengzhong , Chin, Kek Foo , Qiao, Baokun , Zhao, Yan , Yan, Lin , Tan, Choon-Hong , Jiang, Zhiyong . "Catalytic asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates: access to chiral trifluoromethylated tertiary thioethers and thiols."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Chen, Wenchao , Jing, Zhengzhong , Chin, Kek Foo , Qiao, Baokun , Zhao, Yan , Yan, Lin , Tan, Choon-Hong , Jiang, Zhiyong . Catalytic asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates: access to chiral trifluoromethylated tertiary thioethers and thiols. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
|
ridm@nrct.go.th ระบบคลังข้อมูลงานวิจัยไทย รายการโปรดที่คุณเลือกไว้
