| ชื่อเรื่อง | : | RAFT copolymerization of alginate-derived macromonomers - synthesis of a well-defined poly(HEMAm)-graft-(1 4)-α-L-guluronan copolymer capable of ionotropic gelation |
| นักวิจัย | : | Ghadban, Ali , Reynaud, Eric , Rinaudo, Marguerite , Albertin, Luca |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry::Polymers |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2556 |
| อ้างอิง | : | Ghadban, A., Reynaud, E., Rinaudo, M. & Albertin, L. 2013. RAFT copolymerization of alginate-derived macromonomers – synthesis of a well-defined poly(HEMAm)-graft-(1→4)-α-L-guluronan copolymer capable of ionotropic gelation. Polymer Chemistry, 4, 4578-4583. , http://hdl.handle.net/10220/19534 , http://dx.doi.org/10.1039/C3PY00730H |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Polymer chemistry |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | The aqueous RAFT copolymerization of methacrylamide- and methacrylate-functionalized (1→4)-α-L-guluronan and (1→4)-β-D-mannuronan macromonomers with N-(2-hydroxyethyl)methacrylamide afforded synthetic-g-polysaccharide copolymers with a predetermined and well-defined molar mass (“grafting through” approach). One such polymer featuring guluronan graft chains of Xn = 21 was able to undergo ionotropic gelation in the presence of Ca2+ ions and to form a soft hydrogel in spite of the fairly low molar mass (Mn = 77 000 Da). The high yield synthesis of a new methacrylate-functionalized (1→4)-α-L-guluronan is also reported. |
| บรรณานุกรม | : |
Ghadban, Ali , Reynaud, Eric , Rinaudo, Marguerite , Albertin, Luca . (2556). RAFT copolymerization of alginate-derived macromonomers - synthesis of a well-defined poly(HEMAm)-graft-(1 4)-α-L-guluronan copolymer capable of ionotropic gelation.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Ghadban, Ali , Reynaud, Eric , Rinaudo, Marguerite , Albertin, Luca . 2556. "RAFT copolymerization of alginate-derived macromonomers - synthesis of a well-defined poly(HEMAm)-graft-(1 4)-α-L-guluronan copolymer capable of ionotropic gelation".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Ghadban, Ali , Reynaud, Eric , Rinaudo, Marguerite , Albertin, Luca . "RAFT copolymerization of alginate-derived macromonomers - synthesis of a well-defined poly(HEMAm)-graft-(1 4)-α-L-guluronan copolymer capable of ionotropic gelation."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2556. Print. Ghadban, Ali , Reynaud, Eric , Rinaudo, Marguerite , Albertin, Luca . RAFT copolymerization of alginate-derived macromonomers - synthesis of a well-defined poly(HEMAm)-graft-(1 4)-α-L-guluronan copolymer capable of ionotropic gelation. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2556.
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