| ชื่อเรื่อง | : | Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration |
| นักวิจัย | : | Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Li, X., Wu, D., Lu, T., Yi, G., Su, H., & Zhang, Y. (2014). Highly Efficient Chemical Process To Convert Mucic Acid into Adipic Acid and DFT Studies of the Mechanism of the Rhenium-Catalyzed Deoxydehydration. Angewandte Chemie, 126(16), 4284-4288. , 0044-8249 , http://hdl.handle.net/10220/19641 , http://dx.doi.org/10.1002/ange.201310991 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Angewandte chemie |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | The production of bulk chemicals and fuels from renewable bio-based feedstocks is of significant importance for the sustainability of human society. Adipic acid, as one of the most-demanded drop-in chemicals from a bioresource, is used primarily for the large-volume production of nylon-6,6 polyamide. It is highly desirable to develop sustainable and environmentally friendly processes for the production of adipic acid from renewable feedstocks. However, currently there is no suitable bio-adipic acid synthesis process. Demonstrated herein is the highly efficient synthetic protocol for the conversion of mucic acid into adipic acid through the oxorhenium-complex-catalyzed deoxydehydration (DODH) reaction and subsequent Pt/C-catalyzed transfer hydrogenation. Quantitative yields (99 %) were achieved for the conversion of mucic acid into muconic acid and adipic acid either in separate sequences or in a one-step process. |
| บรรณานุกรม | : |
Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . (2557). Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . 2557. "Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . "Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Li, Xiukai , Wu, Di , Lu, Ting , Yi, Guangshun , Su, Haibin , Zhang, Yugen . Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
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