| ชื่อเรื่อง | : | Heteroleptic Germanium(II) and Tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene |
| นักวิจัย | : | Chia, Siew-Peng , Li, Yongxin , Ganguly, Rakesh , So, Cheuk-Wai |
| คำค้น | : | DRNTU::Science::Physics |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Chia, S.-P., Li, Y., Ganguly, R., & So, C.-W. (2014). Heteroleptic Germanium(II) and Tin(II) Chlorides Supported by Anionic Ligands Derived from 2,3-Dimethyl-1,4-diaza-1,3-butadiene. European Journal of Inorganic Chemistry, 2014(3), 526-532. , 1434-1948 , http://hdl.handle.net/10220/19060 , http://dx.doi.org/10.1002/ejic.201300830 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | European journal of inorganic chemistry |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | The syntheses and structures of heteroleptic germanium(II) and tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene are described. The reaction of ArN=C(Me)C(Me)=NAr (L, Ar = 2,6-iPr2C6H3) with MeLi in Et2O, followed by treatment with GeCl2·dioxane or SnCl2, afforded [L1ECl] [L1 = ArN=C(Me)C(Me)2NAr; E = Ge (1), Sn (2)]. Moreover, L2Li [L2 = ArN=C(Me)C(=CH2)NAr] reacted with GeCl2·dioxane in Et2O to form [{C(=CH)NAr}{C(Me)=NAr}]2(GeCl)2 (3). The byproducts are [{C(CH2)NAr}{C(Me)=NAr}Ge]2 (4) and L2H (5). Furthermore, the reaction of L with LiNiPr2 in Et2O, followed by treatment with SnCl2, afforded [L2SnCl] (6). Compounds 1–4 and 6 have been characterized by NMR spectroscopy and X-ray crystallography. |
| บรรณานุกรม | : |
Chia, Siew-Peng , Li, Yongxin , Ganguly, Rakesh , So, Cheuk-Wai . (2557). Heteroleptic Germanium(II) and Tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Chia, Siew-Peng , Li, Yongxin , Ganguly, Rakesh , So, Cheuk-Wai . 2557. "Heteroleptic Germanium(II) and Tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Chia, Siew-Peng , Li, Yongxin , Ganguly, Rakesh , So, Cheuk-Wai . "Heteroleptic Germanium(II) and Tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Chia, Siew-Peng , Li, Yongxin , Ganguly, Rakesh , So, Cheuk-Wai . Heteroleptic Germanium(II) and Tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
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