| ชื่อเรื่อง | : | Synthesis of block copolymers of varying architecture through suppression of transesterification during coordinated anionic ring opening polymerization. |
| นักวิจัย | : | Lipik, Vitali T. , Abadie, Marc J. M. |
| คำค้น | : | - |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2555 |
| อ้างอิง | : | Lipik, V. T., & Abadie, M. J. M. (2012). Synthesis of Block Copolymers of Varying Architecture Through Suppression of Transesterification during Coordinated Anionic Ring Opening Polymerization. International Journal of Biomaterials, 2012, 390947. , http://hdl.handle.net/10220/16939 , http://dx.doi.org/10.1155/2012/390947 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | International journal of biomaterials |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | Well-defined di- and triblock copolymers consisting of ε-caprolactone (CL), L-lactide (LA), and trimethylene carbonate (TMC) were synthesized via “PLA first route” in coordinated anionic ring opening polymerization/copolymerization (CAROP) with tin (II) octoate as catalyst. The desired block structure was preserved by use of protective additive α-methylstyrene by preventing the transesterification side-reactions. MALDI-TOF analysis revealed that the protection mechanism is associated with α-methylstyrene and tin (II) octoate complexation. Additionally, it was shown that use of α-methylstyrene in ring opening polymerization allowed the formation of polyesters with high molar mass. |
| บรรณานุกรม | : |
Lipik, Vitali T. , Abadie, Marc J. M. . (2555). Synthesis of block copolymers of varying architecture through suppression of transesterification during coordinated anionic ring opening polymerization..
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Lipik, Vitali T. , Abadie, Marc J. M. . 2555. "Synthesis of block copolymers of varying architecture through suppression of transesterification during coordinated anionic ring opening polymerization.".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Lipik, Vitali T. , Abadie, Marc J. M. . "Synthesis of block copolymers of varying architecture through suppression of transesterification during coordinated anionic ring opening polymerization.."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print. Lipik, Vitali T. , Abadie, Marc J. M. . Synthesis of block copolymers of varying architecture through suppression of transesterification during coordinated anionic ring opening polymerization.. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.
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