| ชื่อเรื่อง | : | Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines |
| นักวิจัย | : | Xu, Chang , Gan, Kennard Jun Hao , Hennersdorf, Felix , Li, Yongxin , Pullarkat, Sumod A. , Leung, Pak-Hing |
| คำค้น | : | - |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2555 |
| อ้างอิง | : | Xu, C., Gan, K. J. H., Hennersdorf, F., Li, Y., Pullarkat, S. A., & Leung, P.-H. (2012). Chiral Phosphapalladacycles as Efficient Catalysts for the Asymmetric Hydrophosphination of Substituted Methylidenemalonate Esters: Direct Access to Functionalized Tertiary Chiral Phosphines. Organometallics, 31(8), 3022–3026. , http://hdl.handle.net/10220/13698 , http://dx.doi.org/10.1021/om201115n |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Organometallics |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | A chiral palladacycle-promoted enantioselective asymmetric hydrophosphination of substituted methylidenemalonate esters using diphenylphosphine that provides direct access to chiral tertiary phosphines is reported. Screening of three easily accessible C,N and C,P palladacycles as catalysts for this synthetic scenario provided insights into critical factors in catalyst design that influence the activation and stereochemistry in Pd(II)-catalyzed asymmetric P–H addition reactions involving such activated substrates. |
| บรรณานุกรม | : |
Xu, Chang , Gan, Kennard Jun Hao , Hennersdorf, Felix , Li, Yongxin , Pullarkat, Sumod A. , Leung, Pak-Hing . (2555). Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Xu, Chang , Gan, Kennard Jun Hao , Hennersdorf, Felix , Li, Yongxin , Pullarkat, Sumod A. , Leung, Pak-Hing . 2555. "Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Xu, Chang , Gan, Kennard Jun Hao , Hennersdorf, Felix , Li, Yongxin , Pullarkat, Sumod A. , Leung, Pak-Hing . "Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print. Xu, Chang , Gan, Kennard Jun Hao , Hennersdorf, Felix , Li, Yongxin , Pullarkat, Sumod A. , Leung, Pak-Hing . Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.
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