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Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone
นักวิจัย : Xiao, Jinchong , Azuma, Yasuo , Liu, Yi , Li, Gang , Wei, Fengxia , Tan, Ke Jie , Kloc, Christian , Zhang, Hua , Majima, Yutaka , Zhang, Qichun
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Xiao, J., Azuma, Y., Liu, Y., Li, G., Wei, F., Tan, K. J., Kloc, C., Zhang, H., Majima, Y., & Zhang, Q. (2012). Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone. Australian journal of chemistry, 65(12), 1674-1678. , 0004-9425 , http://hdl.handle.net/10220/12648 , http://dx.doi.org/10.1071/CH12325
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Australian journal of chemistry
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

An n-type organic semiconductor 2:3,5:6-bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone (BDQ) has been successfully synthesised and characterised. The single crystal structure of BDQ, determined by single-crystal X-ray crystallography, indicated that BDQ is a planar molecule with strong face-to-face π-π stacking (3.40 Å) and S···S interactions (3.66 Å) between neighbouring molecules, which might be in favour of the effective charge transport. The UV-vis spectrum shows that BDQ has shoulder absorption up to 550 nm (2.25 eV). The electrochemical property displays that the HOMO-LUMO gap of BDQ obtained from the half-wave redox potential is 1.92 eV. The displacement current measurement of BDQ-based devices is demonstrated and discussed.

บรรณานุกรม :
Xiao, Jinchong , Azuma, Yasuo , Liu, Yi , Li, Gang , Wei, Fengxia , Tan, Ke Jie , Kloc, Christian , Zhang, Hua , Majima, Yutaka , Zhang, Qichun . (2555). Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Xiao, Jinchong , Azuma, Yasuo , Liu, Yi , Li, Gang , Wei, Fengxia , Tan, Ke Jie , Kloc, Christian , Zhang, Hua , Majima, Yutaka , Zhang, Qichun . 2555. "Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Xiao, Jinchong , Azuma, Yasuo , Liu, Yi , Li, Gang , Wei, Fengxia , Tan, Ke Jie , Kloc, Christian , Zhang, Hua , Majima, Yutaka , Zhang, Qichun . "Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Xiao, Jinchong , Azuma, Yasuo , Liu, Yi , Li, Gang , Wei, Fengxia , Tan, Ke Jie , Kloc, Christian , Zhang, Hua , Majima, Yutaka , Zhang, Qichun . Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.