| ชื่อเรื่อง | : | Co 2+ /Co + redox tuning in methyltransferases induced by a conformational change at the axial ligand |
| นักวิจัย | : | Kumar, Manoj , Kumar, Neeraj , Hirao, Hajime , Kozlowski, Pawel M. |
| คำค้น | : | - |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2555 |
| อ้างอิง | : | Kumar, M., Kumar, N., Hirao, H., & Kozlowski, P. M. (2012). Co 2+ /Co + Redox Tuning in Methyltransferases Induced by a Conformational Change at the Axial Ligand. Inorganic Chemistry, 51(10), 5533-5538. , 0020-1669 , http://hdl.handle.net/10220/11575 , http://dx.doi.org/10.1021/ic201970k |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Inorganic chemistry |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | Density functional theory and quantum mechanics/molecular mechanics computations predict cob(I)alamin (Co+Cbx), a universal B12 intermediate state, to be a pentacoordinated square pyramidal complex, which is different from the most widely accepted viewpoint of its tetracoordinated square planar geometry. The square pyramidality of Co+Cbx is inspired by the fact that a Co+ ion, which has a dominant d8 electronic configuration, forms a distinctive Co+--H interaction because of the availability of appropriately oriented filled d orbitals. This uniquely H-bonded Co+Cbx may have catalytic relevance in the context of thermodynamically uphill Co2+/Co+ reduction that constitutes an essential component in a large variety of methyltransferases. |
| บรรณานุกรม | : |
Kumar, Manoj , Kumar, Neeraj , Hirao, Hajime , Kozlowski, Pawel M. . (2555). Co 2+ /Co + redox tuning in methyltransferases induced by a conformational change at the axial ligand.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Kumar, Manoj , Kumar, Neeraj , Hirao, Hajime , Kozlowski, Pawel M. . 2555. "Co 2+ /Co + redox tuning in methyltransferases induced by a conformational change at the axial ligand".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Kumar, Manoj , Kumar, Neeraj , Hirao, Hajime , Kozlowski, Pawel M. . "Co 2+ /Co + redox tuning in methyltransferases induced by a conformational change at the axial ligand."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print. Kumar, Manoj , Kumar, Neeraj , Hirao, Hajime , Kozlowski, Pawel M. . Co 2+ /Co + redox tuning in methyltransferases induced by a conformational change at the axial ligand. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.
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