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One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage
นักวิจัย : Rui, Xianhong , Sim, Daohao , Xu, Chen , Liu, Weiling , Tan, Huiteng , Wong, Kangming , Hng, Huey Hoon , Lim, Tuti Mariana , Yan, Qingyu
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Rui, X., Sim, D., Xu, C., Liu, W., Tan, H., Wong, K., et al. (2012). One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage. RSC Advances, 2(3), 1174-1180. , 2046-2069 , http://hdl.handle.net/10220/10410 , http://dx.doi.org/10.1039/c1ra00698c
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : RSC advances
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Uniform carbon-coated single crystalline vanadium dioxide (VO2(B)@C) nanobelts were successfully prepared by using a facile one-pot hydrothermal approach. Sucrose plays a dual role in this hydrothermal process, namely as a carbon precursor for the carbon shell and, as a reductant to reduce V2O5 to VO2(B). The thickness of the carbon coating layer is tunable from 3.0 to 6.9 nm by changing the ratio of the precursors. Although a high carbon content can improve the electrical conductivity of VO2(B)@C nanobelts, a thick carbon coating layer would block the lithium ion diffusion. The optimal thickness is found to be 4.3 nm (carbon content: 6.6 wt%), where the cathode displays superior performance with highly reversible specific capacities, good cycling stabilities and excellent rate capabilities (e.g. 100 mA h g−1 at 12.4 C).

บรรณานุกรม :
Rui, Xianhong , Sim, Daohao , Xu, Chen , Liu, Weiling , Tan, Huiteng , Wong, Kangming , Hng, Huey Hoon , Lim, Tuti Mariana , Yan, Qingyu . (2555). One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Rui, Xianhong , Sim, Daohao , Xu, Chen , Liu, Weiling , Tan, Huiteng , Wong, Kangming , Hng, Huey Hoon , Lim, Tuti Mariana , Yan, Qingyu . 2555. "One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Rui, Xianhong , Sim, Daohao , Xu, Chen , Liu, Weiling , Tan, Huiteng , Wong, Kangming , Hng, Huey Hoon , Lim, Tuti Mariana , Yan, Qingyu . "One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Rui, Xianhong , Sim, Daohao , Xu, Chen , Liu, Weiling , Tan, Huiteng , Wong, Kangming , Hng, Huey Hoon , Lim, Tuti Mariana , Yan, Qingyu . One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.