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Reinforcement of polyether polyurethane with dopamine-modified clay : the role of interfacial hydrogen bonding

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Reinforcement of polyether polyurethane with dopamine-modified clay : the role of interfacial hydrogen bonding
นักวิจัย : Phua, Si Lei , Yang, Liping , Toh, Cher Ling , Huang, Shu , Tsakadze, Zviad , Lau, Soo Khim , Mai, Yiu-Wing , Lu, Xuehong
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Phua, S. L., Yang, L., Toh, C. L., Huang, S., Tsakadze, Z., Lau, S. K., Mai, Y. W., & Lu, X. (2012). Reinforcement of Polyether Polyurethane with Dopamine-Modified Clay: The Role of Interfacial Hydrogen Bonding. ACS Applied Materials & Interfaces, 4(9), 4571-4578. , Phua, S. L., Yang, L., Toh, C. L., Huang, S., Tsakadze, Z., Lau, S. K., et al. (2012). Reinforcement of Polyether Polyurethane with Dopamine-Modified Clay: The Role of Interfacial Hydrogen Bonding. ACS Applied Materials & Interfaces, 4(9), 4571-4578. , 1944-8244 , http://hdl.handle.net/10220/10271 , http://dx.doi.org/10.1021/am300947b
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : ACS applied materials & interfaces
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Dopamine-modified clay (D-clay) was successfully dispersed into polyether polyurethane (PU) by solvent blending. It is found that the incorporation of D-clay into PU gives rise to significant improvements in mechanical properties, including initial modulus, tensile strength, and ultimate elongation, at a very low clay loading. The large reinforcement could be attributed to the hydrogen bonds between the hard segments of PU and stiff D-clay layers that lead to more effective interfacial stress transfer between the polymer and D-clay. Besides, the interactions between D-clay and PU are also stronger than those between Cloisite 30B organoclay and the PU chains. Consequently, at a similar clay loading, the PU/D-clay nanocomposite has much higher storage modulus than the PU/organoclay nanocomposite at elevated temperatures.

บรรณานุกรม :
Phua, Si Lei , Yang, Liping , Toh, Cher Ling , Huang, Shu , Tsakadze, Zviad , Lau, Soo Khim , Mai, Yiu-Wing , Lu, Xuehong . (2555). Reinforcement of polyether polyurethane with dopamine-modified clay : the role of interfacial hydrogen bonding.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Phua, Si Lei , Yang, Liping , Toh, Cher Ling , Huang, Shu , Tsakadze, Zviad , Lau, Soo Khim , Mai, Yiu-Wing , Lu, Xuehong . 2555. "Reinforcement of polyether polyurethane with dopamine-modified clay : the role of interfacial hydrogen bonding".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Phua, Si Lei , Yang, Liping , Toh, Cher Ling , Huang, Shu , Tsakadze, Zviad , Lau, Soo Khim , Mai, Yiu-Wing , Lu, Xuehong . "Reinforcement of polyether polyurethane with dopamine-modified clay : the role of interfacial hydrogen bonding."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Phua, Si Lei , Yang, Liping , Toh, Cher Ling , Huang, Shu , Tsakadze, Zviad , Lau, Soo Khim , Mai, Yiu-Wing , Lu, Xuehong . Reinforcement of polyether polyurethane with dopamine-modified clay : the role of interfacial hydrogen bonding. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.