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Model apatite systems for the stabilization of toxic metals : II, cation and metalloid substitutions in chlorapatites

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Model apatite systems for the stabilization of toxic metals : II, cation and metalloid substitutions in chlorapatites
นักวิจัย : Kim, Jean Y. , Dong, Zhili , White, Timothy John
คำค้น : DRNTU::Engineering::Materials.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2548
อ้างอิง : Kim, J. Y., Dong, Z., & White, T. J. (2005). Model Apatite Systems for the Stabilization of Toxic Metals: II, Cation and Metalloid Substitutions in Chlorapatites. Journal of the American Ceramic Society, 88(5), 1253-1260. , 0002-7820 , http://hdl.handle.net/10220/9476 , http://dx.doi.org/10.1111/j.1551-2916.2005.00136.x
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Journal of the American ceramic society
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Environmental chlorapatites, of the form A10(BxC1−xO4)6Cl2, where A=Ca, Cd, or Pb; B/C=P, V, or Cr and 0≤x≤1, were synthesized by solid-state reactions. Crystal structure variations, primarily lattice parameters, were examined through powder X-ray diffraction methods, while performance and long-term durability of these waste form apatites were assessed by a combination of the toxicity characteristic leaching procedure (TCLP) and the American Nuclear Society (ANS) method. As expected, an overall dilation of unit cell edges was observed with increasing ionic substitutions. However, a discontinuity in linearity was often observed, generally for x≥0.5. The correlation of microstructural changes and leach testing shows that lead chlorapatite is found to be more suitable for waste stabilization than calcium and cadmium analogues.

บรรณานุกรม :
Kim, Jean Y. , Dong, Zhili , White, Timothy John . (2548). Model apatite systems for the stabilization of toxic metals : II, cation and metalloid substitutions in chlorapatites.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Kim, Jean Y. , Dong, Zhili , White, Timothy John . 2548. "Model apatite systems for the stabilization of toxic metals : II, cation and metalloid substitutions in chlorapatites".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Kim, Jean Y. , Dong, Zhili , White, Timothy John . "Model apatite systems for the stabilization of toxic metals : II, cation and metalloid substitutions in chlorapatites."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2548. Print.
Kim, Jean Y. , Dong, Zhili , White, Timothy John . Model apatite systems for the stabilization of toxic metals : II, cation and metalloid substitutions in chlorapatites. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2548.