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9-Aminoacridin-10-ium 4-aminobenzoate dihydrate

หน่วยงาน Universiti Sains Malaysia, Malaysia

รายละเอียด

ชื่อเรื่อง : 9-Aminoacridin-10-ium 4-aminobenzoate dihydrate
นักวิจัย : Santhanaraj, K. Joseph , Dhanabalan, Nallathambi , Thanigaimani, Kaliyaperumal , Arshad, Suhana , Razak, Ibrahim Abdul
คำค้น : QC1-999 Physics
หน่วยงาน : Universiti Sains Malaysia, Malaysia
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : http://eprints.usm.my/37987/1/9%2DAminoacridin%2D10%2Dium_4%2Daminobenzoate.pdf , Dhanabalan, Nallathambi and Thanigaimani, Kaliyaperumal and Arshad, Suhana and Razak, Ibrahim Abdul and Santhanaraj, K. Joseph (2014) 9-Aminoacridin-10-ium 4-aminobenzoate dihydrate. Acta Crystallographica Section E, 2014 (70). 0657-0669. ISSN 1600-5368
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : https://doi.org/10.1107/S160053681401023X , http://eprints.usm.my/37987/
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The asymmetric unit of the title hydrated salt, C13H11N2 +.-C7H6NO2-.2H2O, consists of two independent 9-aminoacridinium cations, two 4-aminobenzoate anions and four water molecules. Both 9-aminoacridinium cations are essentially planar, with maximum deviations of 0.034 (1) and 0.025 (2) A ° , and are protonated at the pyridine N atoms. The 4-aminobenzoate anions are approximately planar, with dihedral angles of 9.16 (19) and 5.4 (2)° between the benzene ring and the carboxylate group. In the crystal, the two independent anions are connected by N—H...O hydrogen bonds, forming a layer parallel to (100). The layers are connected through the cations by N—H...N and N—H...O hydrogen bonds. The water molecules, which form O—H...O hydrogen-bonded chains along the b-axis direction, connect the anions and the cations by O—H...O, N—H...O and C— H...O hydrogen bonds. The crystal structure also features n–n interactions [centroid–centroid distances = 3.6343 (9)– 3.8366 (10) A °] and a C—H...n interaction.

บรรณานุกรม :
Santhanaraj, K. Joseph , Dhanabalan, Nallathambi , Thanigaimani, Kaliyaperumal , Arshad, Suhana , Razak, Ibrahim Abdul . (2557). 9-Aminoacridin-10-ium 4-aminobenzoate dihydrate.
    กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia.
Santhanaraj, K. Joseph , Dhanabalan, Nallathambi , Thanigaimani, Kaliyaperumal , Arshad, Suhana , Razak, Ibrahim Abdul . 2557. "9-Aminoacridin-10-ium 4-aminobenzoate dihydrate".
    กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia.
Santhanaraj, K. Joseph , Dhanabalan, Nallathambi , Thanigaimani, Kaliyaperumal , Arshad, Suhana , Razak, Ibrahim Abdul . "9-Aminoacridin-10-ium 4-aminobenzoate dihydrate."
    กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia, 2557. Print.
Santhanaraj, K. Joseph , Dhanabalan, Nallathambi , Thanigaimani, Kaliyaperumal , Arshad, Suhana , Razak, Ibrahim Abdul . 9-Aminoacridin-10-ium 4-aminobenzoate dihydrate. กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia; 2557.