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The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl

หน่วยงาน Edinburgh Research Archive, United Kingdom

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ชื่อเรื่อง : The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl
นักวิจัย : MacLaughlin, A C , Attfield, J. Paul
คำค้น : Chemistry
หน่วยงาน : Edinburgh Research Archive, United Kingdom
ผู้ร่วมงาน : -
ปีพิมพ์ : 2546
อ้างอิง : The synthesis, structure and physical properties of the layered ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl. Mclaughlin, A. C.; Attfield, J. P. Lecture Notes in Physics (2003), 603 (Ruthenate and Rutheno-Cuprate Materials), 160-175 , 0075-8450 , http://hdl.handle.net/1842/3384 , http://dx.doi.org/10.1002/chin.200336199
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : -
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Studies of the structure and physical properties of the layered rutheno- cuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl are reviewed. RuSr2GdCu2O8 is a weak ferromagnetic superconductor and doping studies have shown that it is possible to tune the magnetic and superconducting transitions simultaneously. The average crystal structure of RuSr2GdCu2O8 is tetragonal at both 10 and 295 K (space group P4/mmm), but a sq.root2a x sq.root2a x c superstructure resulting from coherent rotations of the RuO6 octahedra within subdomains of 50-200 ºA is observed by selected area electron distraction (SAED). The same tilts and rotations of the RuO6 octahedra are observed in semiconducting Pb2Sr2Cu2RuO8Cl, which has strikingly similar magnetic properties to RuSr2GdCu2O8. Antiferromagnetic order is observed in the 10 K neutron diffraction pattern with a Ru moment of 1.1(1) B, but a spin-flop transition is observed above a field of 0.5 T.

บรรณานุกรม :
MacLaughlin, A C , Attfield, J. Paul . (2546). The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl.
    กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom .
MacLaughlin, A C , Attfield, J. Paul . 2546. "The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl".
    กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom .
MacLaughlin, A C , Attfield, J. Paul . "The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl."
    กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom , 2546. Print.
MacLaughlin, A C , Attfield, J. Paul . The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl. กรุงเทพมหานคร : Edinburgh Research Archive, United Kingdom ; 2546.