| ชื่อเรื่อง | : | Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues |
| นักวิจัย | : | Chew, Renta Jonathan , Li, Xi-Rui , Li, Yongxin , Pullarkat, Appukuttan Sumod , Leung, Pak-Hing |
| คำค้น | : | DRNTU::Science::Chemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2558 |
| อ้างอิง | : | Chew, R. J., Li, X.-R., Li, Y., Pullarkat, S. A., & Leung, P.-H. (2015). Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues. Chemistry - A European journal, in press. , 0947-6539 , http://hdl.handle.net/10220/25190 , http://dx.doi.org/10.1002/chem.201406298 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Chemistry - A European journal |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | The palladacycle-catalyzed asymmetric P-H addition of 4-oxo-enamides has been developed, which provides efficient access to phosphinocarboxamides and their analogues. Solvent-mediated reversal of stereoselectivity (ee from +96 % to −92 %) was observed, and the underlying mechanism that allows facile access to both enantiomers of the product by judicious choice of solvents is revealed. |
| บรรณานุกรม | : |
Chew, Renta Jonathan , Li, Xi-Rui , Li, Yongxin , Pullarkat, Appukuttan Sumod , Leung, Pak-Hing . (2558). Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Chew, Renta Jonathan , Li, Xi-Rui , Li, Yongxin , Pullarkat, Appukuttan Sumod , Leung, Pak-Hing . 2558. "Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Chew, Renta Jonathan , Li, Xi-Rui , Li, Yongxin , Pullarkat, Appukuttan Sumod , Leung, Pak-Hing . "Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2558. Print. Chew, Renta Jonathan , Li, Xi-Rui , Li, Yongxin , Pullarkat, Appukuttan Sumod , Leung, Pak-Hing . Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2558.
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