| ชื่อเรื่อง | : | Palladium-catalyzed condensation of N-aryl imines and alkynylbenziodoxolones to form multisubstituted furans |
| นักวิจัย | : | Lu, Beili , Wu, Junliang , Yoshikai, Naohiko |
| คำค้น | : | DRNTU::Science::Chemistry::Organic chemistry |
| หน่วยงาน | : | Nanyang Technological University, Singapore |
| ผู้ร่วมงาน | : | - |
| ปีพิมพ์ | : | 2557 |
| อ้างอิง | : | Lu, B., Wu, J., & Yoshikai, N. (2014). Palladium-catalyzed condensation of N-aryl imines and alkynylbenziodoxolones to form multisubstituted furans. Journal of the American chemical society, 136(33), 11598-11601. , http://hdl.handle.net/10220/24546 , http://dx.doi.org/10.1021/ja5059795 |
| ที่มา | : | - |
| ความเชี่ยวชาญ | : | - |
| ความสัมพันธ์ | : | Journal of the American chemical society |
| ขอบเขตของเนื้อหา | : | - |
| บทคัดย่อ/คำอธิบาย | : | A palladium(II) catalyst promotes condensation of an N-aryl imine and an alkynylbenziodoxolone derivative to afford a multisubstituted furan, whose substituents are derived from the alkynyl moiety (2-position), the imine (3- and 4-positions), and the 2-iodobenzoate moiety (5-position), along with an N-arylformamide under mild conditions. The 2-iodophenyl group of the furan product serves as a versatile handle for further transformations. A series of isotope-labeling experiments shed light on the bond reorganization process in this unusual condensation reaction, which includes cleavage of the C–C triple bond and fragmentation of the carboxylate moiety. NRF (Natl Research Foundation, S’pore) |
| บรรณานุกรม | : |
Lu, Beili , Wu, Junliang , Yoshikai, Naohiko . (2557). Palladium-catalyzed condensation of N-aryl imines and alkynylbenziodoxolones to form multisubstituted furans.
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Lu, Beili , Wu, Junliang , Yoshikai, Naohiko . 2557. "Palladium-catalyzed condensation of N-aryl imines and alkynylbenziodoxolones to form multisubstituted furans".
กรุงเทพมหานคร : Nanyang Technological University, Singapore. Lu, Beili , Wu, Junliang , Yoshikai, Naohiko . "Palladium-catalyzed condensation of N-aryl imines and alkynylbenziodoxolones to form multisubstituted furans."
กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print. Lu, Beili , Wu, Junliang , Yoshikai, Naohiko . Palladium-catalyzed condensation of N-aryl imines and alkynylbenziodoxolones to form multisubstituted furans. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.
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