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Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds
นักวิจัย : Medvedev, Alexander G. , Mikhaylov, Alexey A. , Churakov, Andrei V. , Prikhodchenko, Petr V. , Lev, Ovadia
คำค้น : DRNTU::Engineering::Materials
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Medvedev, A. G., Mikhaylov, A. A., Churakov, A. V., Prikhodchenko, P. V., & Lev, O. (2012). Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds. Acta crystallographica section C crystal structure communications, 68(3), i20-i24. , 0108-2701 , http://hdl.handle.net/10220/20922 , http://dx.doi.org/10.1107/S0108270112006701
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Acta crystallographica section C crystal structure communication
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Diammonium carbonate hydrogen peroxide monosolvate, 2NH4+·CO32-·H2O2, (I), and dicaesium carbonate hydrogen peroxide tris­olvate, 2Cs+·CO32-·3H2O2, (II), were crystallized from 98% hydrogen peroxide. In (I), the carbonate anions and peroxide solvent mol­ecules are arranged on twofold axes. The peroxide mol­ecules act as donors in only two hydrogen bonds with carbonate groups, forming chains along the a and c axes. In the structure of (II), there are three independent Cs+ ions, two of them residing on twofold axes, as are two of the four peroxide mol­ecules, one of which is disordered. Both structures comprise complicated three-dimensional hydro­gen-bonded networks.

บรรณานุกรม :
Medvedev, Alexander G. , Mikhaylov, Alexey A. , Churakov, Andrei V. , Prikhodchenko, Petr V. , Lev, Ovadia . (2555). Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Medvedev, Alexander G. , Mikhaylov, Alexey A. , Churakov, Andrei V. , Prikhodchenko, Petr V. , Lev, Ovadia . 2555. "Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Medvedev, Alexander G. , Mikhaylov, Alexey A. , Churakov, Andrei V. , Prikhodchenko, Petr V. , Lev, Ovadia . "Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Medvedev, Alexander G. , Mikhaylov, Alexey A. , Churakov, Andrei V. , Prikhodchenko, Petr V. , Lev, Ovadia . Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.