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Diameter effect on the sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene

หน่วยงาน Nanyang Technological University, Singapore

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ชื่อเรื่อง : Diameter effect on the sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene
นักวิจัย : Zhang, Kang , Zhang, Qing , Liu, Cao , Marzari, Nicola , Stellacci, Francesco
คำค้น : DRNTU::Engineering::Electrical and electronic engineering.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Zhang, K., Zhang, Q., Liu, C., Marzari, N., & Stellacci, F. (2012). Diameter Effect on the Sidewall Functionalization of Single-Walled Carbon Nanotubes by Addition of Dichlorocarbene. Advanced Functional Materials, 22(24), 5216-5223. , 1616-3028 , http://hdl.handle.net/10220/10424 , http://dx.doi.org/10.1002/adfm.201201777
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Advanced functional materials
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Dichlorocarbene is added to the sidewalls of single-walled carbon nanotubes (SWNTs) with diameters ranging from 1.2 to 2.2 nm. Small diameter SWNTs are found to react much more easily than large diameter SWNTs. Upon functionalization, the conductance could be largely preserved for almost all SWNTs, while an effective bandgap increase for functionalized metallic SWNTs (m-SWNTs) and a bandgap reduction for functionalized semiconducting SWNTs (s-SWNTs) are generally observed. The results suggest that [2 + 1] cycloaddition is an excellent choice of processing, resulting in SWNTs over a large diameter range with electronic properties that are almost unaffected. Furthermore, possible separation of SWNTs according to their diameters could be achieved due to the apparent diameter-dependent reactivity.

บรรณานุกรม :
Zhang, Kang , Zhang, Qing , Liu, Cao , Marzari, Nicola , Stellacci, Francesco . (2555). Diameter effect on the sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Zhang, Kang , Zhang, Qing , Liu, Cao , Marzari, Nicola , Stellacci, Francesco . 2555. "Diameter effect on the sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Zhang, Kang , Zhang, Qing , Liu, Cao , Marzari, Nicola , Stellacci, Francesco . "Diameter effect on the sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Zhang, Kang , Zhang, Qing , Liu, Cao , Marzari, Nicola , Stellacci, Francesco . Diameter effect on the sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.