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Functionalization and reduction of graphene oxide with p-phenylene diamine for electrically conductive and thermally stable polystyrene composites

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Functionalization and reduction of graphene oxide with p-phenylene diamine for electrically conductive and thermally stable polystyrene composites
นักวิจัย : Ma, Hui-Ling , Zhang, Hao-Bin , Hu, Qi-Hui , Li, Wen-Juan , Jiang, Zhi-Guo , Yu, Zhong-Zhen , Dasari, Aravind
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Ma, H.-L., Zhang, H.-B., Hu, Q.-H., Li, W.-J., Jiang, Z.-G., Yu, Z.-Z. et.al. (2012). Functionalization and Reduction of Graphene Oxide with p-Phenylene Diamine for Electrically Conductive and Thermally Stable Polystyrene Composites. ACS Applied Materials & Interfaces, 4(4), 1948-1953. , 1944-8244 , http://hdl.handle.net/10220/10272 , http://dx.doi.org/10.1021/am201654b
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : ACS applied materials & interfaces
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

A facile and efficient approach was developed to simultaneously functionalize and reduce graphene oxide (GO) with p-phenylene diamine (PPD) by simple refluxing. This was possible by the nucleophilic substitution reaction of epoxide groups of GO with amine groups of PPD aided by NH3 solution. As a consequence, electrical conductivity of GO-PPD increased to 2.1 × 102 S/m, which was nearly 9 orders of magnitude higher than that of GO. Additionally, after the incorporation of GO-PPD in polystyrene (PS), the composites exhibited a sharp transition from electrically insulating to conducting behavior with a low percolation threshold of 0.34 vol %, which was attributed to the improved dispersion and the reduction of GO-PPD. Thermal stability of the PS/GO-PPD composite was also 8 °C higher than that of PS.

บรรณานุกรม :
Ma, Hui-Ling , Zhang, Hao-Bin , Hu, Qi-Hui , Li, Wen-Juan , Jiang, Zhi-Guo , Yu, Zhong-Zhen , Dasari, Aravind . (2555). Functionalization and reduction of graphene oxide with p-phenylene diamine for electrically conductive and thermally stable polystyrene composites.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Ma, Hui-Ling , Zhang, Hao-Bin , Hu, Qi-Hui , Li, Wen-Juan , Jiang, Zhi-Guo , Yu, Zhong-Zhen , Dasari, Aravind . 2555. "Functionalization and reduction of graphene oxide with p-phenylene diamine for electrically conductive and thermally stable polystyrene composites".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Ma, Hui-Ling , Zhang, Hao-Bin , Hu, Qi-Hui , Li, Wen-Juan , Jiang, Zhi-Guo , Yu, Zhong-Zhen , Dasari, Aravind . "Functionalization and reduction of graphene oxide with p-phenylene diamine for electrically conductive and thermally stable polystyrene composites."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Ma, Hui-Ling , Zhang, Hao-Bin , Hu, Qi-Hui , Li, Wen-Juan , Jiang, Zhi-Guo , Yu, Zhong-Zhen , Dasari, Aravind . Functionalization and reduction of graphene oxide with p-phenylene diamine for electrically conductive and thermally stable polystyrene composites. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.